# cat /etc/ppp/options 
lock
ipv6 ,
# cat /etc/ppp/ipv6-up.local 
#!/bin/sh

LOGDEVICE=$6

/sbin/dhcp6c -d ppp200
# chmod 755 /etc/ppp/ipv6-up.local 
# cat /etc/dhcp6c.conf 
interface ppp200 {
        send rapid-commit;
        request domain-name-servers;
	request prefix-delegation;
}; 
# grep IPV6 /etc/sysconfig/network
NETWORKING_IPV6=yes
IPV6_DEFAULTDEV="ppp200"
# cat /etc/sysconfig/network-scripts/ifcfg-ppp200 
USERCTL=yes
BOOTPROTO=dialup
DEVICE=ppp200
ETH=eth0
TYPE=xDSL
ONBOOT=yes
FIREWALL=NONE
PING=.
CLAMPMSS=1400
DEFROUTE=yes
SYNCHRONOUS=no
PROVIDER=DSLppp0
PEERDNS=no
DEMAND=no
DNSTYPE=NOCHANGE

# IPv6 Configurations
USER=(redacted)@ipv6.internode.on.net
IPV6INIT=yes

CF_BASE=`basename $CONFIG`
PIDFILE="/var/run/$CF_BASE-adsl.pid"

# PPPoE Config
PPPOE_TIMEOUT=300
PPPOE_EXTRA=""
LCP_FAILURE=3
LCP_INTERVAL=10

# PPPD Config
PPPD_EXTRA="unit 200"
CONNECT_TIMEOUT=30
CONNECT_POLL=6

Added following information (110516)

tank ~ # netstat -rn
Kernel IP routing table
Destination     Gateway         Genmask         Flags   MSS Window  irtt Iface
188.40.2.187    10.206.206.5    255.255.255.255 UGH       0 0          0 tun0
203.16.215.204  0.0.0.0         255.255.255.255 UH        0 0          0 ppp200
10.206.206.5    0.0.0.0         255.255.255.255 UH        0 0          0 tun0
10.206.206.1    10.206.206.5    255.255.255.255 UGH       0 0          0 tun0
59.167.124.216  0.0.0.0         255.255.255.248 U         0 0          0 bond0.300
192.168.31.96   0.0.0.0         255.255.255.248 U         0 0          0 bond0.400
192.168.254.0   0.0.0.0         255.255.255.248 U         0 0          0 eth0
192.168.31.224  0.0.0.0         255.255.255.240 U         0 0          0 bond0.200
192.168.31.240  0.0.0.0         255.255.255.240 U         0 0          0 bond0.100
192.168.235.192 0.0.0.0         255.255.255.240 U         0 0          0 bond0.300
192.168.31.0    0.0.0.0         255.255.255.224 U         0 0          0 bond0
172.27.24.0     10.206.206.5    255.255.255.0   UG        0 0          0 tun0
0.0.0.0         0.0.0.0         0.0.0.0         U         0 0          0 ppp200
tank ~ # ifconfig -a
bond0     Link encap:Ethernet  HWaddr 00:0A:5E:52:E1:C3  
          inet addr:192.168.31.1  Bcast:192.168.31.31  Mask:255.255.255.224
          inet6 addr: fe80::20a:5eff:fe52:e1c3/64 Scope:Link
          UP BROADCAST RUNNING MASTER MULTICAST  MTU:1500  Metric:1
          RX packets:173221488 errors:0 dropped:0 overruns:0 frame:0
          TX packets:185294727 errors:0 dropped:0 overruns:0 carrier:0
          collisions:0 txqueuelen:0 
          RX bytes:1379557404 (1.2 GiB)  TX bytes:185864804 (177.2 MiB)

bond0.100 Link encap:Ethernet  HWaddr 00:0A:5E:52:E1:C3  
          inet addr:192.168.31.254  Bcast:192.168.31.255  Mask:255.255.255.240
          inet6 addr: fe80::20a:5eff:fe52:e1c3/64 Scope:Link
          UP BROADCAST RUNNING MASTER MULTICAST  MTU:1500  Metric:1
          RX packets:91944647 errors:0 dropped:0 overruns:0 frame:0
          TX packets:55292220 errors:0 dropped:0 overruns:0 carrier:0
          collisions:0 txqueuelen:0 
          RX bytes:767508336 (731.9 MiB)  TX bytes:4293493827 (3.9 GiB)

bond0.200 Link encap:Ethernet  HWaddr 00:0A:5E:52:E1:C3  
          inet addr:192.168.31.238  Bcast:192.168.31.239  Mask:255.255.255.240
          inet6 addr: fe80::20a:5eff:fe52:e1c3/64 Scope:Link
          UP BROADCAST RUNNING MASTER MULTICAST  MTU:1500  Metric:1
          RX packets:1936434 errors:0 dropped:0 overruns:0 frame:0
          TX packets:1655338 errors:0 dropped:0 overruns:0 carrier:0
          collisions:0 txqueuelen:0 
          RX bytes:92817782 (88.5 MiB)  TX bytes:144951300 (138.2 MiB)

bond0.300 Link encap:Ethernet  HWaddr 00:0A:5E:52:E1:C3  
          inet addr:59.167.124.222  Bcast:59.167.124.223  Mask:255.255.255.248
          inet6 addr: fe80::20a:5eff:fe52:e1c3/64 Scope:Link
          UP BROADCAST RUNNING MASTER MULTICAST  MTU:1500  Metric:1
          RX packets:4685067 errors:0 dropped:0 overruns:0 frame:0
          TX packets:4478417 errors:0 dropped:0 overruns:0 carrier:0
          collisions:0 txqueuelen:0 
          RX bytes:1247672355 (1.1 GiB)  TX bytes:1024145683 (976.7 MiB)

bond0.300:1 Link encap:Ethernet  HWaddr 00:0A:5E:52:E1:C3  
          inet addr:192.168.235.200  Bcast:192.168.235.207  Mask:255.255.255.240
          UP BROADCAST RUNNING MASTER MULTICAST  MTU:1500  Metric:1

bond0.400 Link encap:Ethernet  HWaddr 00:0A:5E:52:E1:C3  
          inet addr:192.168.31.97  Bcast:192.168.31.103  Mask:255.255.255.248
          inet6 addr: fe80::20a:5eff:fe52:e1c3/64 Scope:Link
          UP BROADCAST RUNNING MASTER MULTICAST  MTU:1500  Metric:1
          RX packets:0 errors:0 dropped:0 overruns:0 frame:0
          TX packets:10 errors:0 dropped:0 overruns:0 carrier:0
          collisions:0 txqueuelen:0 
          RX bytes:0 (0.0 b)  TX bytes:620 (620.0 b)

eth0      Link encap:Ethernet  HWaddr 00:50:FC:AA:71:D6  
          inet addr:192.168.254.3  Bcast:192.168.254.7  Mask:255.255.255.248
          inet6 addr: fe80::250:fcff:feaa:71d6/64 Scope:Link
          UP BROADCAST RUNNING MULTICAST  MTU:1500  Metric:1
          RX packets:37575818 errors:2227 dropped:12177 overruns:1039 frame:0
          TX packets:24189207 errors:0 dropped:0 overruns:0 carrier:0
          collisions:0 txqueuelen:1000 
          RX bytes:1648486133 (1.5 GiB)  TX bytes:2701026933 (2.5 GiB)
          Interrupt:201 Base address:0x2000 

eth1      Link encap:Ethernet  HWaddr 00:0A:5E:52:E1:C3  
          UP BROADCAST RUNNING SLAVE MULTICAST  MTU:1500  Metric:1
          RX packets:173108125 errors:0 dropped:0 overruns:0 frame:0
          TX packets:185294727 errors:0 dropped:0 overruns:0 carrier:0
          collisions:0 txqueuelen:1000 
          RX bytes:1370898747 (1.2 GiB)  TX bytes:185864804 (177.2 MiB)
          Interrupt:185 Memory:df000000-df010000 

eth2      Link encap:Ethernet  HWaddr 00:0A:5E:52:E1:C3  
          UP BROADCAST RUNNING SLAVE MULTICAST  MTU:1500  Metric:1
          RX packets:113363 errors:0 dropped:0 overruns:0 frame:0
          TX packets:0 errors:0 dropped:0 overruns:0 carrier:0
          collisions:0 txqueuelen:1000 
          RX bytes:8658657 (8.2 MiB)  TX bytes:0 (0.0 b)
          Interrupt:193 Memory:df010000-df020000 

lo        Link encap:Local Loopback  
          inet addr:127.0.0.1  Mask:255.0.0.0
          inet6 addr: ::1/128 Scope:Host
          UP LOOPBACK RUNNING  MTU:16436  Metric:1
          RX packets:102706 errors:0 dropped:0 overruns:0 frame:0
          TX packets:102706 errors:0 dropped:0 overruns:0 carrier:0
          collisions:0 txqueuelen:0 
          RX bytes:18571969 (17.7 MiB)  TX bytes:18571969 (17.7 MiB)

ppp200    Link encap:Point-to-Point Protocol  
          inet addr:150.101.xxx.xxx  P-t-P:203.16.215.204  Mask:255.255.255.255
          inet6 addr: fe80::b57d:7875:7182:914e/10 Scope:Link
          UP POINTOPOINT RUNNING NOARP MULTICAST  MTU:1492  Metric:1
          RX packets:312713 errors:0 dropped:0 overruns:0 frame:0
          TX packets:253495 errors:0 dropped:0 overruns:0 carrier:0
          collisions:0 txqueuelen:3 
          RX bytes:254434834 (242.6 MiB)  TX bytes:25002935 (23.8 MiB)

sit0      Link encap:IPv6-in-IPv4  
          NOARP  MTU:1480  Metric:1
          RX packets:0 errors:0 dropped:0 overruns:0 frame:0
          TX packets:0 errors:0 dropped:0 overruns:0 carrier:0
          collisions:0 txqueuelen:0 
          RX bytes:0 (0.0 b)  TX bytes:0 (0.0 b)

tun0      Link encap:UNSPEC  HWaddr 00-00-00-00-00-00-00-00-00-00-00-00-00-00-00-00  
          inet addr:10.206.206.6  P-t-P:10.206.206.5  Mask:255.255.255.255
          UP POINTOPOINT RUNNING NOARP MULTICAST  MTU:1500  Metric:1
          RX packets:675 errors:0 dropped:0 overruns:0 frame:0
          TX packets:729 errors:0 dropped:0 overruns:0 carrier:0
          collisions:0 txqueuelen:100 
          RX bytes:96466 (94.2 KiB)  TX bytes:49763 (48.5 KiB)